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Experiment of the Month #6 – Crystallization

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The winter
holidays are always viewed with great anticipation at our house. Our
children are excited about the holidays and about being out of school
and spending extra time at home. One of our favorite activities during
this time of year is to investigate the chemistry of crystal formation
and create unique and beautiful winter decorations at the same time! Are
you looking for a fun and educational science project your whole family
can participate in during the holidays? Then growing borax snowflakes is
for you. With a little “household science,” you can create long-lasting
crystal snowflakes that are just as sparkling as the real ones. And,
check out the other great science toys and science gifts on our site.

Using a specially designed photo-microscope,
Kenneth Libbrecht the Professor of Physics at the California Institute
of Technology, has spent the last 11 years catching and photographing
tiny snowflakes. |
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Image of the Borax Snowflake
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Concept: |
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Minerals from the earth
sometimes grow into specific three-dimensional geometric shapes called a
crystal. Borax is an example of a crystal. A crystal is a solid with
flat sides and a symmetrical shape. It takes this form because its
molecules are arranged in a unique, repeating pattern. Crystallization
is a separation of solids and liquids when molecules cluster together in
a repeated pattern. As the molecules group together, they try to become
stable or solid. This process is also known as nucleation and is the
beginning of crystal formation. As long as the temperature is consistent
and the molecules outnumber the liquid, crystals will form. If the
molecules cannot join the group, they are reabsorbed back into the
liquid. Stalactites and stalagmites are great examples of natural
crystal formations.
Objective:
To explore the formation of crystals and to observe the crystalline
shape displayed by borax.
Materials:
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String
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Wide mouth jar,
pint size
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White pipe
cleaners
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Borax (Borax is
available at grocery stores in the laundry soap section. 20 Mule
Team Borax Laundry Booster is a good choice. Do not use Boraxo
soap.)
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Pencil
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Boiling water
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Food coloring
(optional)
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Scissors
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Procedure:
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Cut a pipe
cleaner into three equal sections.
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Twist the
sections together at their centers to form a six-sided snowflake
shape (or a heart shape, or a flower, butterfly, you get the idea!).
The ends do not have to be even, you can trim them to get the shape
you want. Make sure your snowflake fits inside the jar.
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Tie the string
to the end of one of the snowflake arms. Tie the other end of the
string to the pencil. The string length should be such that the
pencil just hangs the snowflake into the jar when resting on the top
of the jar.
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Fill the wide
mouth pint jar with boiling water. Add borax one tablespoon at a
time to the boiling water, stirring to dissolve after each addition.
The total amount used is 3 tablespoons borax per 1 cup of water. It
is okay if some un-dissolved borax settles to the bottom of the jar.
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You may tint the
mixture with food color if you wish.
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Hang the pipe
cleaner snowflake into the jar so that the pencil rests on top of
the jar and the snowflake is completely covered with liquid. The
snowflake should hang freely and not touch the bottom of the jar.
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Allow the jar to
sit undisturbed overnight.
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Wow!!
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Place it to dry
over two layers of paper towels. Your snowflake can be used in a
window to catch the sunlight, for decoration or as an ornament.
Questions:
What shape do other crystals take?
Salt
and sugar are examples of crystals that can be formed using the same
technique. How does their shape compare to that of the borax crystals?
You will find that salt crystals are always cube shaped, and snow
crystals always form a six-sided structure.
How do you think the
borax crystals form?
Hot water holds more borax
crystals than cold water. That's because heated water molecules move
farther apart, making room for more of the borax crystals to dissolve.
When no more of the solution can be dissolved, you have reached
saturation. As this water/borax solution cools, the water molecules move
closer together again. Now there's less room for the solution to hold
onto as much of the dissolved borax. Crystals begin to form and build on
one another as the water lets go of the excess and evaporates.
Note: Borax crystals are not
edible. Adult supervision is recommended for this project.
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Crystalline Candy!
You can try this same experiment using
sugar to create your own rock candy! It takes longer for the crystals to
form, but we think rock candy is worth the wait!
Prepare your jar. Cut a clean piece of
string long enough to tie around the stick and dangle 2/3rds of the way
to the bottom of the jar. Wet the string with water and roll it in sugar
to create "seed crystals" for the larger crystals to grow on. Tie it
onto the stick and place the stick over the mouth of the jar, letting
the string dangle in the jar.
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Create a supersaturated sugar solution,
using twice as much sugar as water. Heat the sugar and water over low
heat until the sugar dissolves.
Increase the heat until the mixture
boils, stirring constantly. Allow it to boil without stirring for a
minute.
Pour the sugar solution slowly into the
jar. If your jar is not made of tempered glass, such as a canning jar or
a Pyrex container, warm the glass with hot water to prevent it from
cracking due to the quick change in temperature.
Place the jar in a well lit, warm area
and allow it to sit undisturbed for several days. The longer it sits,
the larger the crystals will grow. Once the crystals reach the desired
size, remove the string, examine your crystals and enjoy.
Be sure to
note the above warning that borax crystals are not edible. Do not
mistakenly confuse your sugar crystals with your borax crystals.
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Get the Ultimate Crystal Growing Kit!
If you
enjoyed this experience, check out our Ultimate Crystal Growing Kit and
other science toys and science gifts. You’ll learn all about the various
forms crystals take, grow giant gems, glowing geodes and an entire
crystal garden!
Go there now! |
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